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1.
国际大洋发现计划(International Ocean Discovery Program, IODP)349航次在南海东部次海盆和西南次海盆残留扩张脊附近的U1431和U1433站位首次钻取基底玄武岩, 通过对16块基底玄武岩内的碳酸盐岩脉薄片镜下观察以及激光拉曼光谱分析, 揭示碳酸盐矿物为方解石和文石, 为典型的洋壳低温热液蚀变次生矿物。U1431站位碳酸盐岩脉为独立的方解石脉、文石脉交替出现; 而U1433站位则存在方解石脉、文石脉和方解石-文石共生脉三种情况。此外, U1431站位在基底~42.1m处出现了平行的方解石脉和文石脉, 揭示U1431存在不同来源热液的多期活动, 即可能存在多次或多阶段不同的热液注入。U1431和U1433站位的碳酸岩脉中, 文石的矿物集合体形状基本一致, 呈块状、纤维状和放射纤维状; 而方解石存在差异, U1431的方解石以斑块状、块状、粒状和纤维状出现, 而U1433的方解石仅出现块状。U1431站位的碳酸盐岩脉的丰度明显高于U1433站位。这些均揭示U1431站位的低温热液活动强, 而U1433站位则相对弱。两个站位的热液活动不同很可能是由于区域地质环境的差异造成——U1431附近的巨大海山为其提供了热液补给, 而U1433远离热液的补给/渗漏点。  相似文献   
2.
In order to model non‐Fickian transport behaviour in groundwater aquifers, various forms of the time–space fractional advection–dispersion equation have been developed and used by several researchers in the last decade. The solute transport in groundwater aquifers in fractional time–space takes place by means of an underlying groundwater flow field. However, the governing equations for such groundwater flow in fractional time–space are yet to be developed in a comprehensive framework. In this study, a finite difference numerical scheme based on Caputo fractional derivative is proposed to investigate the properties of a newly developed time–space fractional governing equations of transient groundwater flow in confined aquifers in terms of the time–space fractional mass conservation equation and the time–space fractional water flux equation. Here, we apply these time–space fractional governing equations numerically to transient groundwater flow in a confined aquifer for different boundary conditions to explore their behaviour in modelling groundwater flow in fractional time–space. The numerical results demonstrate that the proposed time–space fractional governing equation for groundwater flow in confined aquifers may provide a new perspective on modelling groundwater flow and on interpreting the dynamics of groundwater level fluctuations. Additionally, the numerical results may imply that the newly derived fractional groundwater governing equation may help explain the observed heavy‐tailed solute transport behaviour in groundwater flow by incorporating nonlocal or long‐range dependence of the underlying groundwater flow field.  相似文献   
3.
采用室内实验生态学方法,以水体中氨氮、活性磷酸盐和溶氧变化为指标研究了光照强度和光色对番红砗磲代谢的影响。结果表明:(1)在0—10000lx光照时,番红砗磲排氨量逐渐减少,在光照12000lx时转为吸收海水中氨氮,并在16000lx时达到最高[1.89μg/(ind·h)];在2000lx光照条件下,番红砗磲可吸收海水中活性磷酸盐并释放氧气。其活性磷酸盐吸收量随光照强度增强而增加,在16000lx时达到最高峰。在实验光照范围内,番红砗磲产氧率随光照强度的增强逐渐增加。上述结果显示番红砗磲最佳光照强度约为16000lx。(2)当番红砗磲自黑暗转移至各光照组后,其氨氮、活性磷酸盐吸收率均随时间逐渐降低,而产氧率则逐渐升高。(3)光色显著影响番红砗磲合成代谢,蓝光最佳,红光次之,白光最差。  相似文献   
4.
针对第三类反应体系的反应器网络综合问题,提出将串联反应以反应物到目的产物的反应步数为依据的新分段策略。通过比较不分段目的产物、不分段目的产物和中间产品、分段副产物和分段目的产物这四种不同的瞬时选择性,提出以分段副产物瞬时选择性为参数,以其对关键组分浓度或转化率的导数为依据选择各阶段最合适的反应器,以目的产物总选择性最大为目标采用遗传算法优化反应器网络。通过三个实例验证了本文所建立方法在解决复杂反应反应器网络综合问题的有效性,且本方法同样适用于简单反应体系。  相似文献   
5.
运用密度泛函理论(DFT)在ωB97XD/gen (O、H元素Aug-cc-PVDZ; Rb元素Lanl2DZ)基组水平上研究了[Rb(H_2O)_n]~+(n=1~12)水合团簇的结构和光谱学性质。研究结果表明,通过分析气相和液相中的稳定能以及水合团簇可知,稳定构型出现在8配位的团簇中。第一配位层水分子数为8时形成Rb~+第一近似饱和水合层。此外,拉曼光谱显示[Rb(H_2O)_n]~+(n=1~12)水合团簇中O-H伸缩振动峰随着水分子数增加发生移动和加宽,Rb~+发生水合时,O-H对称和非对称伸缩振动发生红移,随着水合数的增多,频率蓝移。此外,文中对拉曼光谱中O-H振动的频率位置结合团簇结构进行了说明。  相似文献   
6.
引入一维加权平均的谱分析方法定量研究四川地形强迫对该区域降水分布的影响。结果表明:纬向地形和冬季降水谱峰锁相于同一波长(475.8 km),呈共振关系,地形与其他季节降水呈漂移关系,这与经向和纬向上环流变动有关,即冬季纬向环流占主导,纬向地形触发的大气波动对冬季降水策动作用大;夏季降水是各种不同尺度系统相互作用的结果,地形是重要因素之一。经向和纬向地形特征尺度分别为296.8 km和475.8 km,反映了地形强迫的中尺度特征,且纬向地形谱峰比经向大1个数量级,纬向强迫更明显。夏季降水谱峰比冬季大2个数量级,降水系统纬向特征尺度比冬季小约150 km,说明夏季在纬向地形强迫下,降水系统尺度减小的同时其强度大大增加,这在一定程度上可以解释中尺度对流性降水在夏季偏多。四川夏季最大降水位于雅安地区,其地形扰动比四川整体扰动更明显,故产生的降水也更大。夏季降水和经向地形锁相于同一波长(37.1 km),经向地形对雅安夏季强降水起关键作用。  相似文献   
7.
This paper presents an efficient methodology for computing constant‐ductility inelastic response spectra. The computation of constant‐ductility spectra involves numerical root‐finding algorithms to find the strongest structure providing a desired ductility response. Smooth inelastic structural behavior is modeled using a first‐order nonlinear differential equation and the transient structural response is solved using an implicit algorithm requiring Newton iterations at each time step. For structural models with smooth hysteretic behavior (not piece‐wise linear), a simple root‐finding method involving a combination of hyperbolic fits, linear interpolation, and Newton's method converges upon the highest strength (conservative) solution with a small number of iterations. The effect of the hysteretic smoothness on the occurrence of multiple roots is examined for two near‐fault and two far‐fault earthquake records, and for two measures of ductility and for normalized hysteretic energy. The results indicate how the smoothness of the hysteretic behavior affects ductility demand and constant‐ductility response spectra. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
8.
The range of response frequencies for which spectral ordinates obtained from accelerograms may be considered reliable is limited by several factors, primary among them being the effects of filters that are routinely applied to remove noise from the records. Considerable attention has been focused on the low‐frequency limit of the usable spectral ordinates because of various engineering applications requiring long‐period spectral accelerations or displacements but only recently have rational approaches to selecting the high‐frequency limit been proposed. Since there are applications for which the high‐frequency spectral ordinates are important, the approaches to this issue presented in the recent studies are reviewed and their application to the ground‐motion database from Europe and the Middle East is explored. On the basis of the results of these analyses, it is concluded that a large proportion of this dataset can be used to provide reliable estimates of response spectral ordinates at much shorter periods than may have previously been considered feasible. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
9.
The paper provides an introduction to fundamental concepts of mathematical modeling of mass transport in fractured porous heterogeneous rocks. Keeping aside many important factors that can affect mass transport in subsurface, our main concern is the multi-scale character of the rock formation, which is constituted by porous domains dissected by the network of fractures. Taking into account the well-documented fact that porous rocks can be considered as a fractal medium and assuming that sizes of pores vary significantly (i.e. have different characteristic scales), the fractional-order differential equations that model the anomalous diffusive mass transport in such type of domains are derived and justified analytically. Analytical solutions of some particular problems of anomalous diffusion in the fractal media of various geometries are obtained. Extending this approach to more complex situation when diffusion is accompanied by advection, solute transport in a fractured porous medium is modeled by the advection-dispersion equation with fractional time derivative. In the case of confined fractured porous aquifer, accounting for anomalous non-Fickian diffusion in the surrounding rock mass, the adopted approach leads to introduction of an additional fractional time derivative in the equation for solute transport. The closed-form solutions for concentrations in the aquifer and surrounding rocks are obtained for the arbitrary time-dependent source of contamination located in the inlet of the aquifer. Based on these solutions, different regimes of contamination of the aquifers with different physical properties can be readily modeled and analyzed.  相似文献   
10.
利用宁夏及邻区的数字测震资料,选取2009年5月至2010年10月间的31个M2.7-ML4.9地震事件的波形记录,以Brune提出的震源谱为平方模型基础,通过消除观测谱中的几何扩散、非弹性衰减、场地响应、仪器响应等影响因素,得到这些地震的震源谱,根据Brune的圆盘震源模型计算并研究地震矩、矩震级、地震应力降、震源尺...  相似文献   
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